Class 12 Chemistry MCQ – Surface Chemistry

1. Which of the following is NOT a type of adsorption?

a) Physical adsorption
b) Chemical adsorption
c) Absorption
d) Ionic adsorption

Answer:

c) Absorption

Explanation:

Absorption is a bulk phenomenon where a substance uniformly enters another. It's not a type of adsorption, which is a surface phenomenon.

2. Which of the following increases with an increase in the surface area of the adsorbent?

a) Rate of adsorption
b) Activation energy
c) Volume of the adsorbent
d) Density of the adsorbent

Answer:

a) Rate of adsorption

Explanation:

The greater the surface area, the more sites are available for adsorption, increasing the rate of adsorption.

3. What type of isotherm is represented by the equation x/m = kP^1/n?

a) Freundlich isotherm
b) Langmuir isotherm
c) BET isotherm
d) Gibbs isotherm

Answer:

a) Freundlich isotherm

Explanation:

The given equation represents the Freundlich isotherm, which relates adsorption to pressure.

4. For which type of adsorption is the heat of adsorption high?

a) Physical adsorption
b) Chemical adsorption
c) Electrostatic adsorption
d) Desorption

Answer:

b) Chemical adsorption

Explanation:

Chemical adsorption involves the formation of chemical bonds, leading to higher heats of adsorption compared to physical adsorption.

5. In a colloid, the dispersed phase is:

a) The medium in which particles are dispersed
b) The particles that are dispersed
c) The solvent
d) The solute

Answer:

b) The particles that are dispersed

Explanation:

In a colloid, the dispersed phase refers to the particles, droplets, or bubbles spread throughout the dispersion medium.

6. Which method is used to purify colloids?

a) Dialysis
b) Centrifugation
c) Distillation
d) Chromatography

Answer:

a) Dialysis

Explanation:

Dialysis is a process used to remove impurities from colloidal solutions using a semi-permeable membrane.

7. The Brownian movement in colloids is caused by:

a) Gravitational force
b) Magnetic field
c) Random motion of molecules
d) Electric field

Answer:

c) Random motion of molecules

Explanation:

The random, zig-zag motion of colloidal particles, known as Brownian movement, is due to the incessant collision with molecules of the dispersion medium.

8. Which type of colloid cannot be coagulated?

a) Lyophilic colloid
b) Lyophobic colloid
c) Multimolecular colloid
d) All colloids can be coagulated

Answer:

d) All colloids can be coagulated

Explanation:

All colloids can be coagulated under suitable conditions, but lyophilic colloids are more resistant to coagulation than lyophobic colloids.

9. Which phenomenon confirms the colloidal nature of a solution?

a) Tyndall effect
b) Osmosis
c) Brownian movement
d) Both a) and c)

Answer:

d) Both a) and c)

Explanation:

Both the Tyndall effect (scattering of light by colloidal particles) and Brownian movement confirm the colloidal nature of a solution.

10. Catalysts that are in the same phase as the reactants are called:

a) Heterogeneous catalysts
b) Homogeneous catalysts
c) Inhibitors
d) Adsorbents

Answer:

b) Homogeneous catalysts

Explanation:

Homogeneous catalysts are in the same phase as the reactants, while heterogeneous catalysts are in a different phase.

11. Which among the following is a macromolecular colloid?

a) Gold sol
b) Starch
c) Milk
d) Soap solution

Answer:

b) Starch

Explanation:

Starch is a natural polymer and forms macromolecular colloids when dispersed in water.

12. The adsorption of gas on solid surface is generally:

a) Exothermic
b) Endothermic
c) Neither exothermic nor endothermic
d) Isothermal

Answer:

a) Exothermic

Explanation:

The process of adsorption is generally exothermic, as energy is released when gas molecules get adsorbed onto a solid surface.

13. Emulsions are:

a) True solutions
b) Suspensions
c) Colloidal solutions
d) Crystalline solids

Answer:

c) Colloidal solutions

Explanation:

Emulsions are a type of colloid in which both the dispersed phase and the dispersion medium are liquids.

14. The stability of a colloidal solution is due to:

a) Gravitational forces
b) Vander Waals forces
c) Charge on colloidal particles
d) Molecular size

Answer:

c) Charge on colloidal particles

Explanation:

The stability of colloids is mainly due to the repulsion between particles carrying the same type of charge.

15. In the adsorption of a gas on a solid, the volume of the gas adsorbed decreases with:

a) Increase in temperature
b) Decrease in temperature
c) Increase in pressure
d) Decrease in pressure

Answer:

a) Increase in temperature

Explanation:

Adsorption is usually exothermic, so increasing temperature will reduce the extent of adsorption, leading to a decrease in the volume of gas adsorbed.

16. Which of the following is NOT a property of colloids?

a) Brownian motion
b) Tyndall effect
c) Osmotic pressure
d) Electrical conductivity

Answer:

d) Electrical conductivity

Explanation:

While some colloids can conduct electricity, it's not a general property of all colloids.

17. What prevents the particles in a lyophobic sol from settling down?

a) Viscosity of the medium
b) Charge on the particles
c) Brownian motion
d) Both b) and c)

Answer:

d) Both b) and c)

Explanation:

The stability of lyophobic sols is maintained by the charge on the particles and their Brownian motion.

18. In surface chemistry, the term "adsorbate" refers to:

a) The substance on which adsorption takes place
b) The substance that is adsorbed
c) The layer of molecules on the surface
d) The forces holding the molecules on the surface

Answer:

b) The substance that is adsorbed

Explanation:

The adsorbate is the substance that gets adsorbed on the surface of another substance.

19. Which phenomenon is responsible for the cleaning action of soaps?

a) Emulsification
b) Tyndall effect
c) Brownian movement
d) Peptization

Answer:

a) Emulsification

Explanation:

Soaps clean surfaces by emulsifying grease and dirt, thereby allowing them to be washed away.

20. What type of colloids is formed when liquid is dispersed in a gas?

a) Aerosol
b) Foam
c) Gel
d) Sol

Answer:

a) Aerosol

Explanation:

Aerosols are colloids where a liquid or solid is dispersed in a gas.

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