Class 12 Chemistry MCQ – Amines

1. Which of the following amines is primary?

a) Dimethylamine
b) Aniline
c) Trimethylamine
d) Diethylamine

Answer:

b) Aniline

Explanation:

Aniline has one alkyl/aryl group attached to the nitrogen, making it a primary amine.

2. The functional group of amines is:

a) -COOH
b) -C=O
c) -OH
d) -NH2

Answer:

d) -NH2

Explanation:

Amines contain the -NH2 functional group.

3. Which of the following reactions distinguishes primary, secondary, and tertiary amines?

a) Acylation
b) Nitration
c) Hoffmann degradation
d) Hinsberg's test

Answer:

d) Hinsberg's test

Explanation:

Hinsberg's test can differentiate between primary, secondary, and tertiary amines based on their reactivity with benzene sulfonyl chloride.

4. Amines react with nitrous acid to form:

a) Amides
b) Nitriles
c) Diazonium salts
d) Isocyanides

Answer:

c) Diazonium salts

Explanation:

Primary aromatic amines react with nitrous acid to produce diazonium salts.

5. Which of the following is a secondary amine?

a) Methylamine
b) Ethylamine
c) Diethylamine
d) Aniline

Answer:

c) Diethylamine

Explanation:

Diethylamine has two alkyl groups attached to the nitrogen atom, making it a secondary amine.

6. Which of the following amines is aromatic in nature?

a) Butylamine
b) Diethylamine
c) Aniline
d) Trimethylamine

Answer:

c) Aniline

Explanation:

Aniline has a benzene ring and is thus an aromatic amine.

7. The correct IUPAC name for (CH3)2NH is:

a) Dimethylamine
b) Methylamine
c) Ethylamine
d) Trimethylamine

Answer:

a) Dimethylamine

Explanation:

It has two methyl groups attached to the nitrogen.

8. Amines can be prepared from halides by:

a) Elimination reaction
b) Substitution reaction
c) Addition reaction
d) Condensation reaction

Answer:

b) Substitution reaction

Explanation:

Alkyl halides react with ammonia in a nucleophilic substitution reaction to produce amines.

9. Which amine gives a foul smell on reaction with chloroform and alcoholic KOH?

a) Primary
b) Secondary
c) Tertiary
d) Quaternary

Answer:

a) Primary

Explanation:

Primary amines react with chloroform and alcoholic KOH to produce isocyanides, which have a foul smell.

10. Gabriel phthalimide synthesis is used for the preparation of:

a) Primary amines
b) Secondary amines
c) Tertiary amines
d) All of the above

Answer:

a) Primary amines

Explanation:

Gabriel phthalimide synthesis is a method for the preparation of primary amines.

11. Which of the following is a heterocyclic amine?

a) Aniline
b) Pyridine
c) Methylamine
d) Ethylamine

Answer:

b) Pyridine

Explanation:

Pyridine is a heterocyclic compound with a nitrogen atom in the ring.

12. The reaction of amines with carbylamine gives:

a) Amides
b) Urea
c) Isocyanides
d) Cyanides

Answer:

c) Isocyanides

Explanation:

Primary amines react with chloroform in the presence of a base to give isocyanides.

13. Which amine can form a salt with hydrochloric acid?

a) Quaternary amine
b) Tertiary amine
c) Secondary amine
d) All of the above

Answer:

d) All of the above

Explanation:

All amines can react with acids to form ammonium salts.

14. Which of the following amines can undergo acylation?

a) Primary
b) Secondary
c) Tertiary
d) Both a and b

Answer:

d) Both a and b

Explanation:

Primary and secondary amines can undergo acylation to form amides.

15. Diazonium salts are usually stable at:

a) High temperature
b) Room temperature
c) Low temperature
d) None of the above

Answer:

c) Low temperature

Explanation:

Diazonium salts are generally stable at low temperatures and decompose at higher temperatures.

16. Aniline on nitration gives:

a) m-nitroaniline
b) p-nitroaniline
c) o-nitroaniline
d) Both b and c

Answer:

d) Both b and c

Explanation:

Aniline on nitration majorly gives p-nitroaniline and o-nitroaniline.

17. Amines have a ______ smell.

a) Fruity
b) Floral
c) Fishy
d) Pleasant

Answer:

c) Fishy

Explanation:

Amines generally have a characteristic fishy odor.

18. Which of the following compounds will not react with nitrous acid?

a) Methylamine
b) Dimethylamine
c) Aniline
d) Trimethylamine

Answer:

d) Trimethylamine

Explanation:

Trimethylamine is a tertiary amine and does not react with nitrous acid.

19. Aniline on oxidation gives:

a) Benzaldehyde
b) Benzoic acid
c) Nitrobenzene
d) Benzene

Answer:

b) Benzoic acid

Explanation:

Aniline on oxidation produces benzoic acid.

20. Which of the following amines will form a water-soluble salt with hydrochloric acid?

a) Aniline
b) Diethylamine
c) Trimethylamine
d) All of the above

Answer:

d) All of the above

Explanation:

All the given amines can react with HCl to form water-soluble ammonium salts.

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